Researches Chemical and Philosophical; Chiefly concerning nitrous oxide: or dephlogisticated nitrous air and its respirationDavy, Humphry, Sir
Science
Researches Chemical and Philosophical; Chiefly concerning nitrous oxide: or dephlogisticated nitrous air and its respiration
Davy, Humphry, Sir
Nitrous oxide
93 grains of the bright yellow acid of 1,5 became, when 6 cubic inches
of gas had been passed through it, orange colored and fuming, whilst
the undissolved gas increased in quantity so much as to render it
impossible to confine it by the solution of potash. When 9 cubic inches
had passed through, it became dark orange. It had gained in weight
2,75 grains, and was become of specific gravity 1,48 nearly. Hence it
was evident that much nitrous gas had passed through it undissolved.
25 cubic inches more of nitrous gas were now slowly sent through it:
it first became of a light olive, then of a dark olive, then of a
muddy green, then of a bright green, and lastly of a blue green. After
its assumption of this color, the gas appeared to pass through it
unaltered, and large globules of fluid, of a darker green than the
rest, remained at the bottom of the cylinder, and when agitated, did
not combine with it. The increase of weight was only 1 grain, and the
acid was of specific gravity 1,474 nearly.
In this experiment it was evident that the unabsorbed nitrous gas
had carried over with it a considerable quantity of nitrous acid. I
endeavoured to correct the errors resulting from this circumstance,
by connecting the curved tube first with a small water apparatus, and
afterwards with a mercurial apparatus; but when the water apparatus
was used, the greater part of the unabsorbed gas was dissolved with
the nitrous acid it held in solution, by the water; and when mercury
was employed, the nitrous acid that came over was decomposed, and the
quantity of nitrous gas evolved, in consequence increased.
As it was possible that a small deficiency of weight might arise from
the red vapor given out during the processes of weighing and examining
the acid in the last experiment, 35 cubic inches of nitrous gas were
very slowly passed through 90 grains of pale nitrous acid, of specific
gravity 1,5: it became of similar appearance to that just described,
had gained in weight 6,75 grains, and was become of specific gravity
1,475.
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