Researches Chemical and Philosophical; Chiefly concerning nitrous oxide: or dephlogisticated nitrous air and its respirationDavy, Humphry, Sir
Science
Researches Chemical and Philosophical; Chiefly concerning nitrous oxide: or dephlogisticated nitrous air and its respiration
Davy, Humphry, Sir
Nitrous oxide
Supposing the truth of these principles according to the logic of the
French nomenclature, there is no acid to which the term nitrous acid
_ought_ to be applied; but as it has been used to signify the acids
holding in solution nitrous gas, it is perhaps better still to apply it
to those substances, than to invent for them new names. A nomenclature,
accurately expressing their constituent parts, would be too complex,
and like all other nomenclatures founded upon theory, liable to
perpetual alterations. Their composition is known from their specific
gravity and their colors; hence it is better to denote it by those
physical properties: thus orange nitrous acid, of specific gravity
1,480, will signify a solution of nitrous gas in nitric acid, in which
the nitric acid is to the nitrous gas, nearly as 87 to 5, and to the
water as 11 to 1.
X. The estimation of the composition of the yellow and orange colored
nitrous acids given in the following table, may be considered as
tolerably accurate, being deduced from the synthetical experiments
in the sixth section, compared with the analytical ones. But as
in the synthetical experiment, when the acid became green, it was
impossible to ascertain the quantity of nitrous gas that passed through
it unabsorbed, and as in the analysis the quantity of nitrous gas
dissolved by the water at different periods of the experiment could not
be ascertained, the accounts of the composition of the green acids must
be considered only as very imperfect approximations to truth.
TABLE I.
_Containing Approximations to the quantities
of NITRIC ACID, NITROUS GAS, and WATER in
NITROUS ACIDS, of different colors and specific
gravities._
+------------------+---+----------+---+--------+-------+---------+
| 100 | | Specific | | Nitric | Water | Nitrous |
| Parts | | Gravity | | Acid | | gas |
+------------------+---+----------+---+--------+-------+---------+
|Sol. Nitric Acid | | 1,504 | c | 91,55 | 8,45 | — — |
|Yellow Nitrous[38]| | 1,502 | o | 90,5 | 8,3 | 1,2 |
|Bright Yellow | o | 1,500 | n | 88,94 | 8,10 | 2,96 |
|Dark Orange | f | 1,480 | t | 86,84 | 7,6 | 5,56 |
|Light Olive‡ | | 1,479 | a | 86,00 | 7,55 | 6,45 |
|Dark Olive‡ | | 1,478 | i | 85,4 | 7,5 | 7,1 |
|Bright Green‡ | | 1,476 | n | 84,8 | 7,44 | 7,76 |
|Blue Green[39] | | 1,475 | | 84,6 | 7,4 | 8,00 |
+------------------+---+----------+---+--------+-------+---------+
‡ = “FOOTNOTE {38}”
[38] The blue green acid is not homogeneal in its composition, it is
composed of the blue green spherules and the bright green acid. The
blue green spherules are of greater specific gravity than the dark
green acid, probably because they contain little or no water.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account