Researches Chemical and Philosophical; Chiefly concerning nitrous oxide: or dephlogisticated nitrous air and its respiration — John Shaqi
Researches Chemical and Philosophical; Chiefly concerning nitrous oxide: or dephlogisticated nitrous air and its respirationDavy, Humphry, Sir
Science
Researches Chemical and Philosophical; Chiefly concerning nitrous oxide: or dephlogisticated nitrous air and its respiration
Davy, Humphry, Sir
Nitrous oxide
[39] The composition of the acids thus marked, is given from
calculations.
TABLE II.
_Binary Proportions of OXYGENE and NITROGENE in
NITRIC and NITROUS ACIDS._[40]
+---------------+---+-------+--------+-------------+-------+-------+
| 100 Parts | |Oxygene| Nitro- | | Nitro-|Oxygene|
| | | | gene | | gene | |
+---------------+---+-------+--------+-------------+-------+-------+
|Nitric Acid | c | 70,50 | 29,50 | | 1 | 2,389 |
+---------------+ o +-------+--------+ +-------+-------+
|Bright yellow | n | 70,10 | 29,90 | | 1 | 2,344 |
| Nitrous | t | | |Proportions. | | |
+---------------+ a +-------+--------+ Nitrogene. +-------+-------+
|Orange coloured| i | 69,63 | 30,37 | Unity. | 1 | 2,292 |
+---------------+ n +-------+--------+ +-------+-------+
|Dark Green | | 69,08 | 30,92 | | 1 | 2,230 |
+---------------+---+-------+--------+-------------+-------+-------+
[40] Nitrous gas contains 44,05 Nitrogene, and 55,95 Oxygene, as has
been said before.
XI. I have before mentioned that dilute nitric acids are incapable of
dissolving so much nitrous gas in proportion to their quantities of
true acid, as concentrated ones. During their absorption of it, they
go through similar changes of color; 330 grains of nitric acid, of
specific gravity 1,36, after 50 cubic inches of gas had been passed
through it, became blue green, and of specific gravity 1,351. It had
gained in weight but 3 grains; and when the nitrous gas was driven
from it by heat into a water apparatus, but 7 cubic inches were
collected.[41]
From the diminution of specific gravity of nitric acid by combination
with nitrous gas, and from the smaller attraction of nitric acid for
nitrous gas, in proportion as it is diluted, it is probable that the
nitrated acids, in their combinations with water, do not contract so
much as[42] nitric acids of the same specific gravities. The affinities
resulting from the small attraction of nitrous gas for water, and its
greater attraction for nitric acid, must be such as to lessen the
affinity of nitric acid and water for each other.
[41] A great portion of it, of course, dissolved in the water with the
nitrous acid carried over.
[42] Their changes of volume, corresponding to changes of temperature,
most probably, are likewise different.
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