Researches Chemical and Philosophical; Chiefly concerning nitrous oxide: or dephlogisticated nitrous air and its respirationDavy, Humphry, Sir
Science
Researches Chemical and Philosophical; Chiefly concerning nitrous oxide: or dephlogisticated nitrous air and its respiration
Davy, Humphry, Sir
Nitrous oxide
On mingling a large quantity of caustic solution of ammoniac with ¼ of
its weight of water, of exactly the same temperature, no alteration
of it was perceptible by a sensible thermometer.—Hence the two
experiments[69] being assumed as data, the intermediate estimations in
the following table, were found by calculation.
[69] Previous to those experiments, I had made a number of others on
the combination of ammoniac with water.—My design was, to ascertain
the diminution of specific gravity for every three grains of ammoniac
absorbed; but this I found impossible. The capillary tube, when
taken out of the phial, always carried with it a minute portion of
the solution, which partially evaporated before it could be again
introduced; and thus the sources of error increased in proportion to
the number of examinations.
TABLE IV.
_Of approximations to the quantities of AMMONIAC,
such as exists in the aëriform state, saturated with
water at 52°, in AQUEOUS AMMONIACAL SOLUTIONS of
different specific gravities._
+----------+-----+----------+--------+
| 100 | | Ammoniac.| Water. |
| Specific | | | |
| Gravity. | | | |
+----------+ +----------+--------+
| 9054 | | 25,37 | 74,63 |
| 9166 | | 22,07 | 77,93 |
| 9255 | | 19,54 | 80,46 |
| 9326 | c | 17,52 | 82,48 |
| 9385 | o | 15,88 | 84,12 |
| 9435 | n | 14,53 | 85,47 |
| 9476 | t | 13,46 | 86,54 |
| 9513 | a | 12,40 | 87,60 |
| 9545 | i | 11,56 | 88,44 |
| 9573 | n | 10,82 | 89,18 |
| 9597 | | 10,17 | 89,83 |
| 9619 | | 9,60 | 90,40 |
| 9684 | | 9,50 | 90,50 |
| 9639 | | 9,09 | 90,91 |
| 9713 | | 7,17 | 92,83 |
+----------+-----+----------+--------+
As yet no mode has been discovered for obtaining
gases in a state of absolute dryness; consequently
we are ignorant of the different quantities
of water they hold in solution at different
temperatures. As far as we are acquainted with
the combinations of ammoniac, there is no state
in which it exists so free from moisture, as when
aëriform, at low temperatures.
That no considerable source of error existed in the two experiments,
is evident from the trifling difference between the estimations of the
quantities of real ammoniac, in the solution of,9684, as found in the
first experiment, and as given by calculation from the last.
The quantity of ammoniac in a solution of specific gravity not in the
table, may be thus determined—find the difference between the two
specific gravities nearest to it in the table; _d_, and the difference
between their quantities of alkali, _b_; likewise the difference
between the given specific gravity and that nearest to it, _c_.
then _d_ : _b_ :: _c_ : _x_
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account