Scientific American Supplement, No. 611, September 17, 1887Various
Science
Scientific American Supplement, No. 611, September 17, 1887
Various
Science -- Periodicals
The original patents on the use of ammonium bicarbonate have, we
understand, long since expired. But the working details of the process
and much of the most successful apparatus have undergone great
development and improvement during late years, all the important
points being covered by patents still in force, and mainly, if not
wholly, in the hands of the one large firm which is now carrying on
the manufacture in this country, and is controlling the market.
The one weak spot of the ammonia-soda process, as we mentioned before,
is its inability to supply hydrochloric acid or chlorine, and so allow
of making bleaching powder. Time after time it has been announced
positively that the problem was solved, that the ammonia-soda makers
had devised a method of producing hydrochloric acid or chlorine, or
both, without the use of sulphuric acid. But the announcements have so
far proved baseless, and at present the Leblanc makers are getting
incredulous, and do not much excite themselves over new statements of
the kind, though they know that if once their rivals had this weapon
in their hands the battle would be over and the Leblanc process doomed
to rapid extinction.
Such is at present the state of the struggle in this great industry,
and the above outline sketch of the two processes is designed to give
some idea of the conditions to such of our readers as may not have any
special knowledge of these manufactures.
At the present moment great interest is being taken in a new process,
about to be put to work on a large scale, which is designed to take up
the cudgels against the ammonia process and enable the Leblanc makers
to continue the fight on something more like equal terms.
We allude to the process proposed and patented by Messrs. Parnell &
Simpson, and about to be worked by the "Lancashire Alkali and Sulphur
Company," at Widnes. We recently had the opportunity of inspecting
fully the plant erected, and of having the method of procedure
explained to us. We look upon the new process as such a spirited
attempt to turn the tide of a long and losing battle, and as so very
interesting on its own merits, that an account of it in these pages
will be thoroughly in place.
The main idea of the process is to combine the "Leblanc" and the
"ammonia-soda" manufacture. But in place of using caustic lime to
decompose the ammonium chloride and get back the ammonia, the "alkali
waste" spoken of above is employed, it being found that not only is
the ammonia driven off, but that also the sulphur in the "waste" is
obtained in a form allowing of its easy utilization, it and the
ammonia combining to form ammonium sulphide, which passes over in
gaseous form from the decomposing apparatus. This ammonium sulphide
is, as we shall see, quite as available for the working of the
ammonia-soda manufacture as pure and simple ammonia, and all the
sulphur can be obtained from it.
Public-domain text, read in full here on John Shaqi.
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