Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
A still more striking illustration of the same method of questioning
Nature is to be found in the investigation of Sir Humphry Davy, on the
composition of water. The voltaic battery which works our telegraphs was
invented by Volta in 1800; and later, during the same year, it was
discovered in London, by Nicholson and Carlisle, that this remarkable
instrument had the power of decomposing water. These physicists at once
recognized that the chief products of the action of the battery on water
were hydrogen and oxygen gases, thus confirming the results of
Cavendish, who, in 1781, had obtained water by combining these
elementary substances; oxygen having been previously discovered in 1775,
and hydrogen, at least, as early as 1766. It was, however, very soon
also observed that there were always formed by the action of the battery
on water, besides these aeriform products, an alkali and an acid, the
alkali collecting around the negative pole, and the acid around the
positive pole of the electrical combination. In regard to the nature of
this acid and alkali, there was the greatest difference of opinion among
the early experimenters on this subject. Cruickshanks supposed that the
acid was nitrous acid, and the alkali ammonia. Desormes, a French
chemist, attempted to prove that the acid was muriatic acid; while
Brugnatelli asserted that a new and peculiar acid was formed, which he
called the electric acid.
It was in this state of the question that Sir Humphry Davy began his
investigation. From the analogies of chemical science, as well as from
the previous experiments of Cavendish and Lavoisier, he was persuaded
that water consisted solely of oxygen and hydrogen gases, and that the
acid and alkali were merely adventitious products. This opinion was
undoubtedly well founded; but, great disciple of Bacon as he was, Davy
felt that his opinion was worth nothing unless substantiated by
experimental evidence, and accordingly he set himself to work to obtain
the required proof.
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