Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
The temperature of the oil is reduced by passing in air to 110deg. F. and
40 pounds of fine common salt per ton added through a sieve. About
one-half of the acid (40 pounds of concentrated commercial hydrochloric
acid) is now poured in and this is followed by the sodium bichromate in
concentrated solution, previously prepared in a small lead vat or
earthen vessel by dissolving 17 pounds of bichromate in 45 pounds
commercial hydrochloric acid. This solution should be added slowly and
should occupy three hours, the whole mass being thoroughly agitated with
air during the addition and for one hour after the last of the bleaching
mixture has been introduced. The whole mixture is now allowed to settle
for one hour and the exhausted chrome liquors are then run off from the
lower pipe to a waste tank. About 40 gallons of water are now run into
the bleached oil and the temperature raised by open steam to 150deg. to
160deg. F. The mass is then allowed to settle over night.
One such wash is sufficient to remove the spent chrome liquor
completely, provided ample time is allowed for settling. A number of
washings given successively with short periods of settling do not remove
the chrome liquors effectually. The success of the operation depends
entirely upon the completeness of settling.
The wash water is drawn off as before and the clear oil run to storage
tanks or to the soap kettle through the upper oil cock.
The waste liquors are boiled with wet steam and the oil skimmed from the
surface, after which the liquors are run out through an oil trap.
By following the above instructions carefully it is possible to bleach
one ton of palm oil with 17 pounds of bichromate of soda and 85 pounds
hydrochloric acid.
The spent liquors should be a bright green color. Should they be of a
yellow or brownish shade insufficient acid has been allowed and more
must be added to render the whole of the oxygen available.
If low grade oils are being treated more chrome will be necessary, the
amount being best judged by conducting the operation as usual and after
the addition of the bichromate, removing a sample of the oil, washing
the sample and noting the color of a rapidly cooled sample.
A little practice will enable the operator to judge the correspondence
between the color to be removed and the amount of bleaching mixture to
be added.
To obtain success with this process the method of working given must be
adhered to even in the _smallest detail_. This applies to the
temperature at which each operation is carried out particularly.
AIR BLEACHING OF PALM OIL.
The method of conducting this process is identical with the chrome
process to the point where the hydrochloric acid is to be added to the
oil. In this method no acid or chrome is necessary, as the active
bleaching agent is the oxygen of the air.
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