Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
The equipment is similar to that of the former process, except that a
wooden tank in which no iron is exposed will suffice to bleach the oil
in. The process depends in rapidity upon the amount of air blown through
the oil and its even distribution. Iron should not be present or exposed
to the oil during bleaching, as it retards the process considerably.
After the impurities have been removed, as outlined under the chrome
process, the temperature of the oil is raised by open steam to boiling.
The steam is then shut off and air allowed to blow through the oil until
it is completely bleached, the temperature being maintained above 150deg.
F. by occasionally passing in steam. Usually a ton of oil is readily and
completely bleached after the air has been passed through it for 18 to
20 hours, provided the oil is thoroughly agitated by a sufficient flow
of air.
If the oil has been allowed to settle over night, it is advisable to run
off the condensed water and impurities by the lower cock before
agitating again the second day.
When the oil has been bleached to the desired color, which can be
determined by removing a sample and cooling, the mass is allowed to
settle, the water run off to a waste tank from which any oil carried
along may be skimmed off and the supernatant clear oil run to the
storage or soap kettle.
In bleaching by this process, while the process consumes more time and
is not as efficient in bleaching the lower grade oils, the cost of
bleaching is less and with a good oil success is more probable, as there
is no possibility of any of the chrome liquors being present in the oil.
These give the bleached oil a green tint when the chrome method is
improperly conducted and they are not removed.
Instead of blowing the air through it, the heater oil may be brought
into contact with the air, either by a paddle wheel arrangement, which,
in constantly turning, brings the oil into contact with the air, or by
pumping the heated oil into an elevated vessel, pierced with numerous
fine holes from which the oil continuously flows back into the vessel
from which the oil is pumped. While in these methods air, light and heat
act simultaneously in the bleaching of the oil, the equipment required
is too cumbersome to be practical.
Recent investigations[1] in bleaching palm oil by oxygen have shown that
not only the coloring matter but the oil itself was affected. In
bleaching palm oil for 30 hours with air the free fatty acid content
rose and titer decreased considerably.
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