The Daguerreian Journal, Vol. I, No. 8, March 1, 1851Various
Science
The Daguerreian Journal, Vol. I, No. 8, March 1, 1851
Various
Daguerreotype; Photography -- Periodicals
If the solarization be very deep, apply the lamp beneath and slightly
warm the plate, pour suddenly off, and without rinsing, quickly apply the
gilding and gild in the usual way. The whole operation must be quickly
performed, or the chlorine soon attracts the shade of the picture.
There may be instances when this solution may prove of advantage, as,
for instance, when black velvet and milk white are wanted in the same
impression. We have seen it operate with pleasing success; but repeat
that _few_ only use it, yet as in a single instance it might be of value,
we have given it. As much of the muriate of ammonia, in common, is
adulterated, we will give a few tests which all can try.
When pure, this salt is totally volatilizable by heat; if a small portion
on being heated on a piece of platinum foil over a spirit lamp leaves any
fixed residue, it is adulterated. It should dissolve entirely in water;
if it leaves an _insoluble residue_ it is adulterated. The impurities
generally found in sal-ammoniac, are sulphate of ammonia, sulphate of
soda, chloride of sodium, and chloride of potassium; neither of these
are considered injurious in the _bleaching solution_. Occasionally it
contains lead, iron, and copper. The presence of sulphuric acid may be
detected by means of a diluted solution of _chloride_ of barium, added to
a weak solution of muriate of ammonia, in water, this will produce a white
precipitate, which is the more copious and dense, the less the liquor
is diluted. If it contains lead add to a small portion of it, contained
in a test tube, a little diluted _sulphuric acid_, or a few drops of a
solution of _sulphate of soda_ (glauber's salt), if the liquid contains
lead there will be prevalent a white powder, or precipitate, this powder
scarcely dissolves at all in diluted acids, but it dissolves in a solution
of caustic of potash: _iron_, mix a solution of the yellow prussiate of
potash with a solution of red prussiate, a few drops of this added to
a weak solution of muriate of ammonia will produce a blue precipitate;
_copper_, pour about half an ounce of the liquid in a test tube, and add
to it a few drops of liquid ammonia, if copper is present, the liquid
will assume a blue color. Sal-ammonia is known by giving out the odor of
ammonia when mixed with caustic of potash: when sal-ammonia possesses a
_brownish_ color, it indicates the presence of charcoal, or empyreumatic
oil; such sal-ammoniac is good for some purposes, but wholly unfit for
_chemical purposes_.
When sal-ammoniac leaves a non-volatile residue, it may contain _sulphate
of soda_. This is the principal cause of failures with the bleaching
solution, as the sulphate of soda has a tendency to blacken rather than
bleach Daguerreian impressions. The sulphate of soda as well as the
chloride of sodium, is often found in unpurified sal-ammoniac to the
amount of ten per cent.
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