Articles of all kinds can be bleached by simply placing them in a weak
solution of the peroxide, leaving them there for a short time, then
taking out and exposing to the air for some time. The best plan of
applying peroxide of hydrogen is the following: Prepare the bleaching
bath by mixing 1 part of peroxide with 4 parts of water. The strength
can be varied; for those goods that only require a very slight bleach
the proportions may be 1 to 12, while for dark goods the proportions
first given may be used. This bath must be used in either a wooden or
earthenware vessel. Metals of all kinds must be avoided, as they lead
to a decomposition of the peroxide, and therefore a loss of material.
To the bath so prepared just enough ammonia should be added to make it
alkaline, a condition that may be ascertained by using a red litmus
paper, which must just turn blue. Into the bath so prepared the
well-scoured goods are entered and worked well, so that they become
thoroughly saturated. They are then lightly wrung and exposed to the
air for some hours, but must not be allowed to get dry, because only
so long as they are moist is the bleaching going on; if they get dry
the goods should be re-entered into the bath and again exposed to the
air.
If one treatment is not sufficient the process should be repeated. The
peroxide bath is not exhausted, and only requires new material to (p. 036)
be added to it in sufficient quantity to enable the goods to be
readily and easily worked in the liquor. Any degree of whiteness may
be obtained with a sufficient number of workings. No further treatment
is necessary. It is found in practice that an alkaline bath gives the
best results.
Another plan of preparing the bleaching bath is to prepare a bath with
peroxide and water as before, then add to a sufficient quantity of a
solution of silicate of soda 4 parts of water to 1 of silicate of soda
at 100 deg. Tw., to make the bath alkaline. Into this bath the goods are
entered and are then exposed to the air as before, after which they
may be passed through a weak bath of sulphurous acid, being next well
washed in water and dried.
The advantage of bleaching with peroxide is that, as it leaves only
water in the goods as the result of action, there is no danger of
their becoming tendered by an after development of acid due to
defective washing, as is the case with the sulphur bleach. The goods
never alter in colour afterwards, because there is nothing left in
that will change colour. Some bleachers add a little magnesia to the
bath, but this is not at all necessary.
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