The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
“Tho’ the force of its elasticity is so great as to be able to bear a
prodigious pressure, without losing that elasticity, yet we have, from
the foregoing Experiments, evident proof that its elasticity is easily,
and in great abundance destroyed; and is thereby reduced to a fixt
state by the strong attraction of the acid sulphureous particles which
arise either from fire or from fermentation; and therefore _elasticity_
is not an _essential immutable property_ of air-particles; but they
are, we see, easily changed from an elastick to a fixt state, by the
strong attraction of the acid, sulphureous, and saline particles
which abound in air. Whence it is reasonable to conclude that our
atmosphere is a _Chaos_, consisting not only of elastick, but also
of unelastick air-particles, which in plenty float in it, as well as
the sulphureous, saline, watery, and earthy particles, which are no
ways capable of being thrown off into a permanently elastick state,
like those particles which constitute true permanent air. Since, then,
air is found so manifestly to abound in almost all natural bodies;
since we find it so operative and active a principle in every chymical
operation; since its constituent parts are of so durable a nature, that
the most violent action of fire or fermentation cannot induce such an
alteration of its texture as thereby to disqualify it from resuming,
either by the means of fire or fermentation, its former elastick state;
unless in the case of vitrification, when, with the vegetable Salt and
Nitre in which it is incorporated, it may, perhaps, some of it, with
other chymical principles, be immutably fixt,--since then this is the
case, may we not with good reason adopt this now fixt, now volatile
_Proteus_ among the chymical principles, and that a very active one, as
well as acid sulphur; notwithstanding it has hitherto been overlooked
and rejected by chymists, as no way intitled to that denomination?”
This quotation shows us how little Mayow’s shrewd reasoning and
well-devised experiments had impressed the thinkers of his age. While
Hales quotes frequently from Boyle’s and Newton’s works, his reference
to Mayow is meagre; nor does he adopt any one of Mayow’s conclusions.
One would have thought that, having prepared so many gases by means
of apparatus well adapted to their purpose, and having observed that
certain substances introduced into air produced contraction, he would
have drawn the conclusion that such “airs” were essentially different
kinds of matter. But the “Proteus” was too much for him; and he left
the subject practically in the same state of “Chaos” in which he found
it.
[1] _Memoirs for a General History of the Air_; Shaw’s Abridgment of
Boyle’s works, edition 1725, vol. iii. p. 26.
[2] “Suspicions about some hidden qualities of the Air,” _ibid._ p. 77.
CHAPTER II
“FIXED AIR” AND “MEPHITIC AIR”--THEIR DISCOVERY BY BLACK AND
BY RUTHERFORD
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