The Gases of the Atmosphere: The History of Their Discovery — John Shaqi
The Gases of the Atmosphere: The History of Their DiscoveryRamsay, William
History
The Gases of the Atmosphere: The History of Their Discovery
Ramsay, William
Air; Argon; Chemistry -- History
Before relating the history of the discoveries of Black, Rutherford,
and Priestley, it will be appropriate to give an account of a theory
which professed to explain the phenomena of combustion, and with it the
conversion of metals into calces, and the reduction of these calces to
the reguline or metallic state. Like other theories, it was slow in
developing. Its germ is to be traced to the writings of Johann Baptist
van Helmont of Brabant, Seigneur of Merode, Royenboch, Oorshot, and
Pellines, who was born in Brussels in 1577. He adopted a fantastical
creation of Paracelsus, the _archaeus_, a kind of demon which, by means
of fermentation, draws together all the particles of matter. Believing
that water was the true principle and origin of everything (for he had
succeeded in producing a willow tree, weighing 164 lbs., from water
alone, the earth in which it grew having neither gained nor lost
appreciably in weight), he conceived that it was acted on by a
_ferment_ or principle pre-existing in the seed developed by it, and
exhaling an odour by which the archaeus was attracted. Water undergoing
the action of this ferment developed a vapour, to which van Helmont
gave the name of “gas.” A “gas” was a substance intermediate between
spirit and matter, and the word was probably derived from _Geist_, the
common German word for spirit. Another word introduced by him to denote
the life-principle of the stars was _Blas_, connected probably with
_blasen_, to blow, and our English word _blast_.
It is curious to notice how the idea of an _archaeus_ survived down to
later times under the name of a “life-principle”--a conception that all
organic substances must necessarily owe their origin to life itself,
and not to the usual chemical and physical transformations.
Van Helmont was acquainted with various kinds of gases, as appears
from his treatise “De Flatibus.” His _gas sylvestre_ was evolved from
fermenting liquors, and he knew that it was formed during the
combustion of charcoal, and also that it was present in the Grotto del
Cane near Naples. He was likewise acquainted with combustible gases,
which he named _gas pingue_, _gas siccum_, or _gas fuliginosum_.
These principles of van Helmont’s apparently suggested to his
successors, Becher and Stahl, the notion of a principle inherent in
every combustible substance, which was lost during combustion. The
development of this--the phlogistic--theory is almost wholly due to the
latter chemist, and indeed it is difficult to trace Becher’s share in
it.
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