The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
This we readily understand by looking at Fig. 14, in which the solid
shown in outline may be either an egg-shaped figure of revolution, or
may be such a figure flattened by compression perpendicular to the
plane of the diagram. The most readily chosen and the most stable
resting-places for the constituents of each successive layer might be
the wider hollows _p′ q′ r′_: and therefore if, from a single layer to
begin with, the assemblage were to grow by layer after layer added to
it on each side, it might probably grow as a twin-crystal. But it might
also be that the presence of a molecule in the wider hollow _p′ q′ r′_
on one side, might render the occupation of the corresponding hollow on
the other side by another molecule less probable, or even impossible.
Hence, according to the configuration and the molecular forces of the
particular crystalline molecule in natural crystallization, there may
be necessarily, or almost necessarily, the twin, when growth proceeds
simultaneously on the two sides: or the twin growth may be impossible,
because the first occupation of the wider hollows on one side, may
compel the continuity of the crystalline quality throughout, by leaving
only the narrower hollows _p q r_ free for occupation by molecules
attaching themselves on the other side.
§ 39. Or the character of the crystalline molecule may be such
that when the assemblage grows by the addition of layer after layer
on one side only, with a not very strongly decided preference to the
wider hollows _p′ q′ r′_, some change of circumstances may cause
the molecules of one layer to place themselves in a hollow _p q r_.
The molecules in the next layer after this would find the hollows
_p′ q′ r′_ occupied on the far side, and would thus have a bias in
favour of the hollows _p q r_. Thus layer after layer might be added,
constituting a twinned portion of the growth, growing, however,
with less strong security for continued homogeneousness than when
the crystal was growing, as at first, by occupation of the wider
hollows _p′ q′ r′_. A slight disturbance might again occur, causing
the molecules of a fresh layer to settle, not in the narrow hollows
_p q r_, but in the wider hollows _p′ q′ r′_, notwithstanding the
nearness of molecules already occupying the wider hollows on the
other side. Disturbances such as these occurring irregularly during
the growth of a crystal, might produce a large number of successive
twinnings at parallel planes with irregular intervals between them,
or a large number of twinnings in planes at equal intervals might be
produced by some regular periodic disturbance occurring for a certain
number of periods, and then ceasing. Whether regular and periodic, or
irregular, the tendency would be that the number of twinnings should
be even, and that after the disturbances cease the crystal should
go on growing in the first manner, because of the permanent bias in
favour of the wider hollows _p′ q′ r′_. These changes of molecular
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account