The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
tactics, which we have been necessarily led to by the consideration
of the fortuitous concourse of molecules, are no doubt exemplified in
a large variety of twinnings and counter-twinnings found in natural
minerals. In the artificial crystallization of chlorate of potash they
are of frequent occurrence, as is proved, not only by the twinnings and
counter-twinnings readily seen in the crystalline forms, but also by
the brilliant iridescence observed in many of the crystals found among
a large multitude, which was investigated scientifically by Sir George
Stokes ten years ago, and described in a communication to the Royal
Society ‘On a remarkable phenomenon of crystalline reflection’ (_Proc.
R.S._, vol. xxxviii, 1885, p. 174).
§ 40. A very interesting phenomenon, presented by what was originally
a clear homogeneous crystal of chlorate of potash, and was altered by
heating to about 245°-248° Cent., which I am able to show you through
the kindness of Lord Rayleigh, and of its discoverer, Mr. Madan,
presents another very wonderful case of changing molecular tactics,
most instructive in respect of the molecular constitution of elastic
solids. When I hold this plate before you with the perpendicular to
its plane inclined at 10° or more to your line of vision, you see a
tinsel-like appearance, almost as bright as if it were a plate of
polished silver, on this little area, which is a thin plate of chlorate
of potash cemented for preservation between two pieces of glass; and,
when I hold a light behind, you see that the little plate is almost
perfectly opaque like metal foil. But now when I hold it nearly
perpendicular to your line of vision the tinsel-like appearance is
lost. You can see clearly through the plate, and you also see that very
little light is reflected from it. As a result both of Mr. Madan’s own
investigations, and further observations by himself, Lord Rayleigh came
to the conclusion that the almost total reflection of white light which
you see is due to the reflection of light at many interfacial planes
between successive layers of twinned and counter-twinned crystal of
small irregular thicknesses, and not to any splits or cavities or any
other deviation from homogeneousness than that presented by homogeneous
portions of oppositely twinned-crystals in thorough molecular contact
at the interfaces.
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