The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
§ 41. When the primitive clear crystal was first heated very gradually
by Madan to near its melting-point (359° according to Carnelly), it
remained clear, and only acquired the tinsel appearance after it had
cooled to about 245° or 248°[12]. Rayleigh found that if a crystal
thus altered was again and again heated it always lost the tinsel
appearance, and became perfectly clear at some temperature considerably
below the melting-point, and regained it at about the same temperature
in cooling. It seems, therefore, certain that at temperatures above
248°, and below the melting-point, the molecules had so much of thermal
motions as to keep them hovering about the positions of _p q r_, _p′ q′
r′_, of our diagrams, but not enough to do away with the rigidity of
the solid; and that when cooled below 248° the molecules were allowed
to settle in one or other of the two configurations, but with little
of bias for one in preference to the other. It is certainly a very
remarkable fact in Natural History, discovered by these observations,
that, when the molecules come together to form a crystal out of the
watery solution, there should be so much more decided a bias in favour
of continued homogeneousness of the assemblage than when, by cooling,
they are allowed to settle from their agitations in a rigid, but nearly
melting, solid.
§ 42. But even in crystallization from watery solution of chlorate of
potash the bias in favour of thorough homogeneousness is not in every
contingency decisive. In the first place, beginning, as the formation
seems to begin, from a single molecular plane layer such as that
ideally shown in Fig. 14, it goes on, not to make a homogeneous crystal
on the two sides of this layer, but probably always so as to form a
twin-crystal on its two sides, exactly as described in § 38, and, if
so, certainly for the reason there stated. This is what Madan calls
the ‘inveterate tendency to produce twins (such as would assuredly
drive a Malthus to despair)[13]’; and it is to this that he alludes as
‘the inevitable twin-plate’ in the passage from his paper given in the
foot-note to § 41 above.
Public-domain text, read in full here on John Shaqi.
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