The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
substitute a model composed of left-handed molecules such as those
shown in Fig. 17.
§ 50. To give all the qualities of symmetry and anti-symmetry of
the pyro-electric and piezo-electric properties of tourmaline
investigated theoretically by Voigt[22], and experimentally by himself
and Friecke[23], make a hollow in one terminal face of each of our
constituent prisms, and a corresponding projection in its other
terminal face.
§ 51. Coming back to quartz, we can now understand perfectly the
two kinds of macling which are well known to mineralogists as being
found in many natural specimens of the crystal, and which I call
respectively the orientational macling, and the chiral macling.
In the orientational macling all the crystalline molecules are
right-handed, or all left-handed; but through all of some part of the
crystal, each of our component hexagonal prisms is turned round its
axis through 60° from the position it would have if the structure
were homogeneous throughout. In each of the two parts the structure
is homogeneous, and possesses all the electric and optic properties
which any homogeneous portion of quartz crystal presents, and the
facial properties of natural uncut crystal, shown in the etching by
hydrofluoric acid; but there is a discontinuity at the interface, not
generally plane, between the two parts, which in our geometrical model
would be shown by non-fittings between the molecules on the two sides
of the interface, while all the contiguous molecules in one part, and
all the contiguous molecules in the other part, fit into one another
perfectly. In chiral macling, which is continually found in amethystine
quartz, and sometimes in ordinary clear quartz crystals, some parts
are composed of right-handed molecules, and others of left-handed
molecules. It is not known whether, in this chiral macling, there is or
there is not also the orientational macling on the two sides of each
interface; but we may say probably _not_; because we know that the
orientational macling occurs in nature without any chiral macling, and
because there does not seem reason to expect that chiral macling would
imply orientational macling on the two sides of the same interface.
I would like to have spoken to you more of this most interesting
subject; and to have pointed out to you that some of the simplest and
most natural suppositions we can make as to the chemical forces (or
electrical forces, which probably means the same thing) concerned in
a single chemical molecule of quartz, _SiO_{2}_, and acting between
it and similar neighbouring molecules, would lead essentially to
these molecules coming together in triplets, each necessarily either
right-handed or left-handed, but with as much probability of one
configuration as of the other: and to have shown you that these
triplets of silica 3(_SiO_{2}_) can form a crystalline molecule with
all the properties of ternary chiral symmetry, typified by our grooved
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