The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
The extent to which a given clay will vitrify depends on the amount of
fluxing material (metallic compounds, and oxides other than ferric oxide
and alumina) it contains, on the smallness of its particles and on the
duration and intensity of the heating. Clays containing alkalies and
lime compounds vitrify with great rapidity when once the necessary
temperature has been reached, so that unless great care is exercised the
action will proceed too far and the goods will be warped and twisted or
may even form a rough slag. Refractory clays, on the contrary, vitrify
more slowly and at much higher temperatures so that accidental
overheatings of them are far less common.
The difference between the temperature at which sintering
or vitrification occurs and that at which the clay melts
completely--usually termed the 'vitrification range'--varies with the
nature of the clay. In some cases the clay melts as soon as
vitrification becomes noticeable, in others the vitrification occurs at
a dull red heat, but the material does not lose its shape until after a
prolonged heating at the highest temperature of a firebrick kiln or
testing furnace.
Calcareous clays have the melting and sintering points close together,
so that it is almost impossible to produce vitrified and impervious ware
from them, as they lose their shape too readily. If, however, the
difference between the sintering and fusing temperatures can be
enlarged--that is, if the vitrification range can be extended--more
impervious ware can be made. The easiest means of extending the
vitrification range consists in regulating the proportion of large and
small particles. The former increase and the latter diminish the range.
Basic compounds and fluxes cause a lowering of the melting-point and a
shortening of the vitrification range.
The _porosity_ of raw clay is usually of small importance, but the
porosity of fired clay or ware is often a serious factor in determining
the suitability of certain articles for their intended purposes. In its
natural state, clay does not readily absorb much water; on the contrary
it becomes pasty and impervious unless it is disturbed and its texture
destroyed, when it may be mixed with water to form a paste or, with more
water, a thin 'cream' or 'slurry.'
When heated moderately, clay forms a porous material and, unless the
heating is excessive, it will absorb about one-eighth of its weight of
water. Further heating at a higher temperature reduces its porosity--the
more easily fused material filling some of the pores--until a stage is
reached when the material is completely vitrified and is no longer
porous.
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