The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Thus in the building up of similar molecules in crystalline forms we
see one of the numerous means for judging of the internal world of
molecules and atoms, and one of the weapons for conquests in the
invisible world of molecular mechanics which forms the main object of
physico-chemical knowledge. This method[5] has more than once been
employed for discovering the analogy of elements and of their compounds;
and as crystals are measurable, and the capacity to form crystalline
mixtures can be experimentally verified, this method is a numerical and
measurable one, and in no sense arbitrary.
[5] The property of solids of occurring in regular crystalline
forms--the occurrence of many substances in the earth's crust in
these forms--and those geometrical and simple laws which govern the
formation of crystals long ago attracted the attention of the
naturalist to crystals. The crystalline form is, without doubt, the
expression of the relation in which the atoms occur in the
molecules, and in which the molecules occur in the mass, of a
substance. Crystallisation is determined by the distribution of the
molecules along the direction of greatest cohesion, and therefore
those forces must take part in the crystalline distribution of
matter which act between the molecules; and, as they depend on the
forces binding the atoms together in the molecules, a very close
connection must exist between the atomic composition and the
distribution of the atoms in the molecule on the one hand, and the
crystalline form of a substance on the other hand; and hence an
insight into the composition may be arrived at from the crystalline
form. Such is the elementary and _a priori_ idea which lies at the
base of all researches into _the connection between composition and
crystalline form_. Haüy in 1811 established the following
fundamental law, which has been worked out by later investigators:
That the fundamental crystalline form for a given chemical compound
is constant (only the combinations vary), and that with a change of
composition the crystalline form also changes, naturally with the
exception of such limiting forms as the cube, regular octahedron,
&c., which may belong to various substances of the regular system.
The fundamental form is determined by the angles of certain
fundamental geometric forms (prisms, pyramids, rhombohedra), or the
ratio of the crystalline axes, and is connected with the optical
and many other properties of crystals. Since the establishment of
this law the description of definite compounds in a solid state is
accompanied by a description (measurement) of its crystals, which
forms an invariable, definite, and measurable character. The most
important epochs in the further history of this question were made
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