The Principles of Chemistry, Volume II — John Shaqi
The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
by the following discoveries:--Klaproth, Vauquelin, and others
showed that aragonite has the same composition as calc spar, whilst
the former belongs to the rhombic and the latter to the hexagonal
system. Haüy at first considered that the composition, and after
that the arrangement, of the atoms in the molecules was different.
This is dimorphism (_see_ Chapter XIV., Note 46). Beudant,
Frankenheim, Laurent, and others found that the forms of the two
nitres, KNO_{3} and NaNO_{3}, exactly correspond with the forms of
aragonite and calc spar; that they are able, moreover, to pass from
one form into another; and that the difference of the forms is
accompanied by a small alteration of the angles, for the angle of
the prisms of potassium nitrate and aragonite is 119°, and of
sodium nitrate and calc spar, 120°; and therefore dimorphism, or
the crystallisation of one substance in different forms, does not
necessarily imply a great difference in the distribution of the
molecules, although some difference clearly exists. The researches
of Mitscherlich (1822) on the dimorphism of sulphur confirmed this
conclusion, although it cannot yet be affirmed that in dimorphism
the arrangement of the atoms remains unaltered, and that only the
molecules are distributed differently. Leblanc, Berthier,
Wollaston, and others already knew that many substances of
different composition appear in the same forms, and crystallise
together in one crystal. Gay-Lussac (1816) showed that crystals of
potash alum continue to grow in a solution of ammonia alum. Beudant
(1817) explained this phenomenon as the _assimilation_ of a foreign
substance by a substance having a great force of crystallisation,
which he illustrated by many natural and artificial examples. But
Mitscherlich, and afterwards Berzelius and Henry Rose and others,
showed that such an assimilation only exists with a similarity or
approximate similarity of the forms of the individual substances
and with a certain degree of chemical analogy. Thus was established
the idea of _isomorphism_ as an analogy of forms by reason of a
resemblance of atomic composition, and by it was explained the
variability of the composition of a number of minerals as
isomorphous mixtures. Thus all the garnets are expressed by the
general formula: (RO)_{3}M_{2}O_{3}(SiO_{2})_{3}, where R = Ca, Mg,
Fe, Mn, and M = Fe, Al, and where we may have either R and M
separately, or their equivalent compounds, or their mixtures in all
possible proportions.
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