The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
But other facts, which render the correlation of form and
composition still more complex, have accumulated side by side with
a mass of data which may be accounted for by admitting the
conceptions of isomorphism and dimorphism. Foremost among the
former stand the phenomena of _homeomorphism_--that is, a nearness
of forms with a difference of composition--and then the cases of
polymorphism and hemimorphism--that is, a nearness of the
fundamental forms or only of certain angles for substances which
are near or analogous in their composition. Instances of
homeomorphism are very numerous. Many of these, however, may be
reduced to a resemblance of atomic composition, although they do
not correspond to an isomorphism of the component elements; for
example, CdS (greenockite) and AgI, CaCO_{3} (aragonite) and
KNO_{3}, CaCO_{3} (calc spar) and NaNO_{3}, BaSO_{4} (heavy spar),
KMnO_{4} (potassium permanganate), and KClO_{4} (potassium
perchlorate), Al_{2}O_{3} (corundum) and FeTiO_{3} (titanic iron
ore), FeS_{2} (marcasite, rhombic system) and FeSAs (arsenical
pyrites), NiS and NiAs, &c. But besides these instances there are
homeomorphous substances with an absolute dissimilarity of
composition. Many such instances were pointed out by Dana.
Cinnabar, HgS, and susannite, PbSO_{4}3PbCO_{3} appear in very
analogous crystalline forms; the acid potassium sulphate
crystallises in the monoclinic system in crystals analogous to
felspar, KAlSi_{3}O_{8}; glauberite, Na_{2}Ca(SO_{4})_{2}, augite,
RSiO_{3} (R = Ca, Mg), sodium carbonate, Na_{2}CO_{3},10H_{2}O,
Glauber's salt, Na_{2}SO_{4},10H_{2}O, and borax,
Na_{2}BrO_{7},10H_{2}O, not only belong to the same system
(monoclinic), but exhibit an analogy of combinations and a nearness
of corresponding angles. These and many other similar cases might
appear to be perfectly arbitrary (especially as a _nearness_ of
angles and fundamental forms is a relative idea) were there not
other cases where a resemblance of properties and a distinct
relation in the variation of composition is connected with a
resemblance of form. Thus, for example, alumina, Al_{2}O_{3}, and
water, H_{2}O, are frequently found in many pyroxenes and
amphiboles which only contain silica and magnesia (MgO, CaO, FeO,
MnO). Scheerer and Hermann, and many others, endeavoured to explain
such instances by _polymetric isomorphism_, stating that MgO may be
replaced by 3H_{2}O (for example, olivine and serpentine), SiO_{2}
by Al_{2}O_{3} (in the amphiboles, talcs), and so on. A certain
number of the instances of this order are subject to doubt, because
many of the natural minerals which served as the basis for the
establishment of polymeric isomorphism in all probability no longer
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