The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
present their original composition, but one which has been altered
under the influence of solutions which have come into contact with
them; they therefore belong to the class of _pseudomorphs_, or
false crystals. There is, however, no doubt of the existence of a
whole series of natural and artificial homeomorphs, which differ
from each other by atomic amounts of water, silica, and some other
component parts. Thus, Thomsen (1874) showed a very striking
instance. The metallic chlorides, RCl_{2}, often crystallise with
water, and they do not then contain less than one molecule of water
per atom of chlorine. The most familiar representative of the order
RCl_{2},2H_{2}O is BaCl_{2},2H_{2}O, which crystallises in the
rhombic system. Barium bromide, BaBr_{2},2H_{2}O, and copper
chloride, CuCl_{2},2H_{2}O, have nearly the same forms: potassium
iodate, KIO_{4}; potassium chlorate, KClO_{4}; potassium
permanganate, KMnO_{4}; barium sulphate, BaSO_{4}; calcium
sulphate, CaSO_{4}; sodium sulphate, Na_{2}SO_{4}; barium formate,
BaC_{2}H_{2}O_{4}, and others have almost the same crystalline form
(of the rhombic system). Parallel with this series is that of the
metallic chlorides containing RCl_{2},4H_{2}O, of the sulphates of
the composition RSO_{4},2H_{2}O, and the formates
RC_{2}H_{2}O_{4},2H_{2}O. These compounds belong to the monoclinic
system, have a close resemblance of form, and differ from the first
series by containing two more molecules of water. The addition of
two more molecules of water in all the above series also gives
forms of the monoclinic system closely resembling each other; for
example, NiCl_{2},6H_{2}O and MnSO_{4},4H_{2}O. Hence we see that
not only is RCl_{2},2H_{2}O analogous in form to RSO_{4} and
RC_{2}H_{2}O_{4}, but that their compounds with 2H_{2}O and with
4H_{2}O also exhibit closely analogous forms. From these examples
it is evident that the conditions which determine a given form may
be repeated not only in the presence of an isomorphous
exchange--that is, with an equal number of atoms in the
molecule--but also in the presence of an unequal number when there
are peculiar and as yet ungeneralised relations in composition.
Thus ZnO and Al_{2}O_{3} exhibit a close analogy of form. Both
oxides belong to the rhombohedral system, and the angle between the
pyramid and the terminal plane of the first is 118° 7´, and of the
second 118° 49´. Alumina, Al_{2}O_{3}, is also analogous in form to
SiO_{2}, and we shall see that these analogies of form are
conjoined with a certain analogy in properties. It is not
surprising, therefore, that in the complex molecule of a siliceous
compound it is sometimes possible to replace SiO_{2} by means of
Al_{2}O_{3}, as Scheerer admits.
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