The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The oxides Cu_{2}O, MgO, NiO,
Fe_{3}O_{4}, CeO_{2}, crystallise in the regular system, although
they are of very different atomic structure. Marignac demonstrated
the perfect analogy of the forms of K_{2}ZrF_{6} and CaCO_{3}, and
the former is even dimorphous, like the calcium carbonate. The same
salt is isomorphous with R_{2}NbOF_{5} and R_{2}WO_{2}F_{4}, where
R is an alkali metal. There is an equivalency between CaCO_{3} and
K_{2}ZrF_{6}, because K_{2} is equivalent to Ca, C to Zr, and F_{6}
to O_{3}, and with the isomorphism of the other two salts we find
besides an equal contents of the alkali metal--an equal number of
atoms on the one hand and an analogy to the properties of
K_{2}ZrF_{6} on the other. The long-known isomorphism of the
corresponding compounds of potassium and ammonium, KX and NH_{4}X,
may be taken as the simplest example of the fact that an analogy of
form shows itself with an analogy of chemical reaction even without
an equality in atomic composition. Therefore the ultimate progress
of the entire doctrine of the correlation of composition and
crystalline forms will only be arrived at with the accumulation of
a sufficient number of facts collected on a plan corresponding with
the problems which here present themselves. The first steps have
already been made. The researches of the Geneva _savant_, Marignac,
on the crystalline form and composition of many of the double
fluorides, and the work of Wyruboff on the ferricyanides and other
compounds, are particularly important in this respect. It is
already evident that, with a definite change of composition,
certain angles remain constant, notwithstanding that others are
subject to alteration. Such an instance of the relation of forms
was observed by Laurent, and named by him _hemimorphism_ (an
anomalous term) when the analogy is limited to certain angles, and
_paramorphism_ when the forms in general approach each other, but
belong to different systems. So, for example, the angle of the
planes of a rhombohedron may be greater or less than 90°, and
therefore such acute and obtuse rhombohedra may closely approximate
to the cube. Hausmannite, Mn_{3}O_{4}, belongs to the tetragonal
system, and the planes of its pyramid are inclined at an angle of
about 118°, whilst magnetic iron ore, Fe_{3}O_{4}, which resembles
hausmannite in many respects, appears in regular octahedra--that
is, the pyramidal planes are inclined at an angle of 109° 28´. This
is an example of paramorphism; the systems are different, the
compositions are analogous, and there is a certain resemblance in
form. Hemimorphism has been found in many instances of saline and
other substitutions. Thus, Laurent demonstrated, and Hintze
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