The Principles of Chemistry, Volume II — John Shaqi
The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
confirmed (1873), that naphthalene derivatives of analogous
composition are hemimorphous. Nicklès (1849) showed that in
ethylene sulphate the angle of the prism is 125° 26´, and in the
nitrate of the same radicle 126° 95´. The angle of the prism of
methylamine oxalate is 131° 20´, and of fluoride, which is very
different in composition from the former, the angle is 132°. Groth
(1870) endeavoured to indicate in general what kinds of change of
form proceed with the substitution of hydrogen by various other
elements and groups, and he observed a regularity which he termed
_morphotropy_. The following examples show that morphotropy recalls
the hemimorphism of Laurent. Benzene, C_{6}H_{6}, rhombic system,
ratio of the axes 0·891 : 1 : 0·799. Phenol, C_{6}H_{5}(OH), and
resorcinol, C_{6}H_{4}(OH)_{2}, also rhombic system, but the ratio
of one axis is changed--thus, in resorcinol, 0·910 : 1 : 0·540;
that is, a portion of the crystalline structure in one direction is
the same, but in the other direction it is changed, whilst in the
rhombic system dinitrophenol, C_{6}H_{3}(NO_{2})_{2}(OH) =
O·833 : 1 : 0·753; trinitrophenol (picric acid),
C_{6}H_{2}(NO)_{3}(OH) = 0·937 : 1 : 0·974; and the potassium salt
= 0·942 : 1 : 1·354. Here the ratio of the first axis is
preserved--that is, certain angles remain constant, and the
chemical proximity of the composition of these bodies is undoubted.
Laurent compares hemimorphism with architectural style. Thus,
Gothic cathedrals differ in many respects, but there is an analogy
expressed both in the sum total of their common relations and in
certain details--for example, in the windows. It is evident that we
may expect many fruitful results for molecular mechanics (which
forms a problem common to many provinces of natural science) from
the further elaboration of the data concerning those variations
which take place in crystalline form when the composition of a
substance is subjected to a known change, and therefore I consider
it useful to point out to the student of science seeking for matter
for independent scientific research this vast field for work which
is presented by the correlation of form and composition. The
geometrical regularity and varied beauty of crystalline forms offer
no small attraction to research of this kind.
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