The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The regularity and simplicity expressed by the exact laws of crystalline
form repeat themselves in the aggregation of the atoms to form molecules.
Here, as there, there are but few forms which are essentially different,
and their apparent diversity reduces itself to a few fundamental
differences of type. There the molecules aggregate themselves into
crystalline forms; here, the atoms aggregate themselves into molecular
forms or into _the types of compounds_. In both cases the fundamental
crystalline or molecular forms are liable to variations, conjunctions,
and combinations. If we know that potassium gives compounds of the
fundamental type KX, where X is a univalent element (which combines with
one atom of hydrogen, and is, according to the law of substitution, able
to replace it), then we know the composition of its compounds: K_{2}O,
KHO, KCl, NH_{2}K, KNO_{3}, K_{2}SO_{4}, KHSO_{4},
K_{2}Mg(SO_{4})_{2},6H_{2}O, &c. All the possible derivative crystalline
forms are not known. So also all the atomic combinations are not known
for every element. Thus in the case of potassium, KCH_{3}, K_{3}P,
K_{2}Pt, and other like compounds which exist for hydrogen or chlorine,
are unknown.
Only a few fundamental types exist for the building up of atoms into
molecules, and the majority of them are already known to us. If X stand
for a univalent element, and R for an element combined with it, then
eight atomic types may be observed:--
RX, RX_{2}, RX_{3}, RX_{4}, RX_{5}, RX_{6}, RX_{7}, RX_{8}.
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