The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
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The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
atomic weight of an element may sometimes be corrected by aid of a
knowledge of those of the adjacent elements. Thus the combining
weight of tellurium must lie between 123 and 126, and cannot be
128. (8) Certain characteristic properties of the elements can be
foretold from their atomic weights.
The entire periodic law is included in these lines. In the series
of subsequent papers (1870-72, for example, in the _Transactions_
of the Russian Chemical Society, of the Moscow Meeting of
Naturalists, of the St. Petersburg Academy, and Liebig's _Annalen_)
on the same subject we only find applications of the same
principles, which were afterwards confirmed by the labours of
Roscoe, Carnelley, Thorpe, and others in England; of Rammelsberg
(cerium and uranium), L. Meyer (the specific volumes of the
elements), Zimmermann (uranium), and more especially of C. Winkler
(who discovered germanium, and showed its identity with
ekasilicon), and others in Germany; of Lecoq de Boisbaudran in
France (the discoverer of gallium = ekaaluminium); of Clève (the
atomic weights of the cerium metals), Nilson (discoverer of
scandium = ekaboron), and Nilson and Pettersson (determination of
the vapour density of beryllium chloride) in Sweden; and of Brauner
(who investigated cerium, and determined the combining weight of
tellurium = 125) in Austria, and Piccini in Italy.
I consider it necessary to state that, in arranging the periodic
system of the elements, I made use of the previous researches of
Dumas, Gladstone, Pettenkofer, Kremers, and Lenssen on the atomic
weights of related elements, but I was not acquainted with the
works preceding mine of De Chancourtois (_vis tellurique_, or the
spiral of the elements according to their properties and
equivalents) in France, and of J. Newlands (Law of Octaves--for
instance, H, F, Cl, Co, Br, Pd, I, Pt form the first octave, and O,
S, Fe, Se, Rh, Te, Au, Th the last) in England, although certain
germs of the periodic law are to be seen in these works. With
regard to the work of Prof. Lothar Meyer respecting the periodic
law (Notes 12 and 13), it is evident, judging from the method of
investigation, and from his statement (Liebig's _Annalen, Supt.
Band 7_, 1870, 354), at the very commencement of which he cites my
paper of 1869 above mentioned, that he accepted the periodic law in
the form which I proposed.
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