The Principles of Chemistry, Volume II — John Shaqi
The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
With respect to this remarkable parallelism, it must above all be
observed that in the elements the atomic weight increases in
passing to contiguous members of a higher valency, whilst here it
decreases, which should indicate that the periodic variability of
elements and compounds is subject to some higher law whose nature,
and still more whose cause, cannot at present be determined. It is
probably based on the fundamental principles of the internal
mechanics of the atoms and molecules, and as the periodic law has
only been generally recognised for a few years it is not
surprising that any further progress towards its explanation can
only be looked for in the development of facts touching on this
subject.
1. The composition of the higher oxygen compounds is determined by the
groups: the first group gives R_{2}O, the second R_{2}O_{2} or RO, the
third R_{2}O_{3}, &c. There are eight types of oxides and therefore eight
groups. Two groups give a period, and the same type of oxide is met with
twice in a period. For example, in the period beginning with potassium,
oxides of the composition RO are formed by calcium and zinc, and of the
composition RO_{3} by molybdenum and tellurium. The oxides of the even
series, of the same type, have stronger basic properties than the oxides
of the uneven series, and the latter as a rule are endowed with an acid
character. Therefore the elements which exclusively give bases, like the
alkali metals, will be found at the commencement of the period, whilst
such purely acid elements as the halogens will be at the end of the
period. The interval will be occupied by intermediate elements, whose
character and properties we shall afterwards describe. It must be
observed that the acid character is chiefly proper to the elements with
small atomic weights in the uneven series, whilst the basic character is
exhibited by the heavier elements in the even series. Hence elements
which give acids chiefly predominate among the lightest (typical)
elements, especially in the last groups; whilst the heaviest elements,
even in the last groups (for instance, thallium, uranium) have a basic
character. Thus the basic and acid characters of the higher oxides are
determined (_a_) by the type of oxide, (_b_) by the even or uneven
series, and (_c_) by the atomic weight.[11 bis] The groups are indicated
by Roman numerals from I. to VIII.
2. _The hydrogen compounds_ being volatile or gaseous substances which
are prone to reaction--such as HCl, H_{2}O, H_{3}N, and H_{4}C[12]--are
only formed by the elements of the uneven series and higher groups giving
oxides of the forms R_{2}O_{_n_}, RO_{3}, R_{2}O_{5}, and RO_{2}.
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