The Principles of Chemistry, Volume II — John Shaqi
The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
3. If an element gives a hydrogen compound, RX_{_m_}, it forms an
_organo-metallic compound_ of the same composition, where X =
C_{_n_}H_{2_n_ + 1}; that is, X is the radicle of a saturated
hydrocarbon. The elements of the uneven series, which are incapable of
giving hydrogen compounds, and give oxides of the forms RX, RX_{2},
R_{X}3, also give organo-metallic compounds of this form proper to the
higher oxides. Thus zinc forms the oxide ZnO, salts ZnX_{2} and zinc
ethyl Zn(C_{2}H_{5})_{2}. The elements of the even series do not seem to
form organo-metallic compounds at all; at least all efforts for their
preparation have as yet been fruitless--for instance, in the case of
titanium, zirconium, or iron.
4. The atomic weights of elements belonging to contiguous periods differ
approximately by 45; for example, K<Rb, Cr<Mo, Br<I. But the elements of
the typical series show much smaller differences. Thus the difference
between the atomic weights of Li, Na, and K, between Ca, Mg, and Be,
between Si and C, between S and O, and between Cl and F, is 16. As a
rule, there is a greater difference between the atomic weights of two
elements of one group and belonging to two neighbouring series (Ti-Si =
V-P = Cr-S = Mn-Cl = Nb-As, &c. = 20); and this difference attains a
maximum with the heaviest elements (for example, Th-Pb = 26, Bi-Ta = 26,
Ba-Cd = 25, &c.). Furthermore, the difference between the atomic weights
of the elements of even and uneven series also increases. In fact, the
differences between Na and K, Mg and Ca, Si and Ti, are less abrupt than
those between Pb and Th, Ta and Bi, Cd and Ba, &c. Thus even in the
magnitude of the differences of the atomic weights of analogous elements
there is observable a certain connection with the gradation of their
properties.[12 bis]
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