The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
5. According to the periodic system every element occupies a certain
position, determined by the group (indicated in Roman numerals) and
series (Arabic numerals) in which it occurs. These indicate the atomic
weight, the analogues, properties, and type of the higher oxide, and of
the hydrogen and other compounds--in a word, all the chief quantitative
and qualitative features of an element, although there yet remain a whole
series of further details and peculiarities whose cause should perhaps be
looked for in small differences of the atomic weights. If in a certain
group there occur elements, R_{1}, R_{2}, R_{3}, and if in that series
which contains one of these elements, for instance R_{2}, an element
Q_{2} precedes it and an element T_{2} succeeds it, then the properties
of R_{2} are determined by the properties of R_{1}, R_{3}, Q_{2}, and
T_{2}. Thus, for instance, the atomic weight of R_{2} = 1/4(R_{1} +
R_{3} + Q_{2} + T_{2}). For example, selenium occurs in the same group as
sulphur, S = 32, and tellurium, Te = 125, and, in the 7th series As = 75
stands before it and Br = 80 after it. Hence the atomic weight of
selenium should be 1/4(32 + 125 + 75 + 80) = 78, which is near to the
truth. Other properties of selenium may also be determined in this
manner. For example, arsenic forms H_{3}As, bromine gives HBr, and it is
evident that selenium, which stands between them, should form H_{2}Se,
with properties intermediate between those of H_{3}As and HBr. Even the
physical properties of selenium and its compounds, not to speak of their
composition, being determined by the group in which it occurs, may be
foreseen with a close approach to reality from the properties of sulphur,
tellurium, arsenic, and bromine. _In this manner it is possible to
foretell the properties of still unknown elements._ For instance in the
position IV, 5--that is, in the IVth group and 5th series--an element is
still wanting. These unknown elements may be named after the preceding
known element of the same group by adding to the first syllable the
prefix _eka_-, which means _one_ in Sanskrit. The element IV, 5, follows
after IV, 3, and this latter position being occupied by silicon, we call
the unknown element ekasilicon and its symbol Es. The following are the
properties which this element should have on the basis of the known
properties of silicon, tin, zinc, and arsenic. Its atomic weight is
nearly 72, higher oxide EsO_{2}, lower oxide EsO, compounds of the
general form EsX_{4}, and chemically unstable lower compounds of the form
EsX_{2}. Es gives volatile organo-metallic compounds--for instance,
Es(CH_{3})_{4}, Es(CH_{3})_{3}Cl, and Es(C_{2}H_{5})_{4}, which boil at
about 160°, &c.; also a volatile and liquid chloride, EsCl_{4}, boiling
at about 90° and of specific gravity about 1·9. EsO_{2} will be the
anhydride of a feeble colloidal acid, metallic Es will be rather easily
obtainable from the oxides and from K_{2}EsF_{6} by reduction, EsS_{2}
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account