The Principles of Chemistry, Volume II — John Shaqi
The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
will resemble SnS_{2} and SiS_{2}, and will probably be soluble in
ammonium sulphide; the specific gravity of Es will be about 5·5, EsO_{2}
will have a density of about 4·7, &c. Such a prediction of the properties
of ekasilicon was made by me in 1871, on the basis of the properties of
the elements analogous to it: IV, 3, = Si, IV, 7 = Sn, and also II, 5 =
Zn and V, 5 = As. And now that this element has been discovered by C.
Winkler, of Freiberg, it has been found that its actual properties
entirely correspond with those which were foretold.[13] In this we see a
most important confirmation of the truth of the periodic law. This
element is now called germanium, Ge (_see_ Chapter XVIII.). It is not the
only one that has been predicted by the periodic law.[14] We shall see in
describing the elements of the third group that properties were foretold
of an element ekaaluminium, III, 5, El = 68, and were afterwards verified
when the metal termed 'gallium' was discovered by De Boisbaudran. So also
the properties of scandium corresponded with those predicted for
ekaboron, according to Nilson.[15]
[11 bis] True peroxides (_see_ Note 7), like H_{2}O_{2}, BaO_{2},
S_{2}O_{7} (Chapter XX.), must not be confused with true saline
oxides even if the latter contain much oxygen (for instance,
N_{2}O_{5}, CrO_{3}, &c.) although one and the other easily
oxidise. The difference between them is seen in their fundamental
properties: the saline oxides correspond to water, while the
peroxides correspond in their reactions and origin to peroxide of
hydrogen. This is clearly seen in the difference between Na_{2}O
and Na_{2}O_{2} (Chapter XII.). Therefore the peroxides should
also have their periodicity. An element R, giving a highest degree
of oxidation, R_{2}O_{_n_}, may give both a lower degree of
oxidation, R_{2}O_{_n_ - _m_} (where _m_ is evidently less than
_n_), and peroxides, R_{2}O_{_n_ + 1}, R_{2}O_{_n_ + 2}, or even
more oxygen. This class of oxides, to which attention has only
recently been turned (Berthelot, Piccini, &c.), may perhaps on
further study give the possibility of generalising the capability
of the elements to give unstable complex higher forms of
combination, such as double salts, and in my opinion should in the
near future be the field of new and important discoveries. And in
contemporary chemistry, salts, saline oxides, hydrogen compounds,
and other combinations of the elements corresponding to them
constitute an important and very complex problem for
generalisation, which is satisfied by the periodic law in its
present form, to which it has risen from its first state, in which
it gave the means of foreseeing (_see_ later on) the existence of
unknown elements (Ga, Sc, and Ge), their properties, and many
details respecting their compounds. Until those improvements in
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