The Principles of Chemistry, Volume IIMendeleyev, Dmitry Ivanovich
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The Principles of Chemistry, Volume II
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
the periodic system which have been proposed by Prof. Flavitzky
(of Kazan) and Prof. Harperath (of Cordoba, in the Argentine
Republic), Ugo Alvisi (Italy), and others give similar practical
results, I think it unnecessary to discuss them further.
[12] The hydrides generalised by the periodic law are those to which
metallo-organic compounds correspond, and they are themselves
either volatile or gaseous. The hydrogen compounds like Na_{2}H,
BaH, &c. are distinguished by other signs. They resemble alloys.
They show (_see_ end of last chapter) a systematic harmony, but
they evidently should not be confused with true hydrides, any more
than peroxides with saline oxides. Moreover, such hydrides have,
like the peroxides, only recently been subjected to research, and
have been but little studied. The best known of these compounds
are given in the 16th column of Table III., and it will be seen
that they already exhibit a periodicity of properties and
composition.
[12 bis] The relation between the atomic weights, and especially the
difference = 16, was observed in the sixth and seventh decades of
this century by Dumas, Pettenkofer, L. Meyer, and others. Thus
Lothar Meyer in 1864, following Dumas and others, grouped together
the tetravalent elements carbon and silicon; the trivalent
elements nitrogen, phosphorus, arsenic, antimony, and bismuth; the
bivalent oxygen, sulphur, selenium, and tellurium; the univalent
fluorine, chlorine, bromine, and iodine; the univalent metals
lithium, sodium, potassium, rubidium, cæsium, and thallium, and
the bivalent metals beryllium, magnesium, strontium and
barium--observing that in the first the difference is, in general
= 16, in the second about = 46, and the last about = 87-90. The
first germs of the periodic law are visible in such observations
as these. Since its establishment this subject has been most fully
worked out by Ridberg (Note 10), who observed a periodicity in the
variation of the differences between the atomic weights of two
contiguous elements, and its relation to their atomicity. A.
Bazaroff (1887) investigated the same subject, taking, not the
arithmetical differences of contiguous and analogous elements, but
the ratio of their atomic weights; and he also observed that this
ratio alternately rises and falls with the rise of the atomic
weights. I will here remark that the relation of the eighth group
to the others will be considered at the end of this work in
Chapter XXII.
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