History, Modern -- 19th century; Nineteenth century
metals, to which he gave the names calcium, strontium, and barium.
Distillation removed most of the mercury, and the metal was left
behind in a state of comparative purity. The alkali metals, potassium
and sodium, were found to attack glass, liberating “the basis of the
silex,” to which the name silicon has since been given.
Thus nearly the last of the “earths” had been decomposed. It was proved
that not merely were the “calces” of iron, copper, lead, and other
well-known metals compounds of the respective metals with oxygen, but
Davy showed that lime, and its allies, strontia and baryta, and even
silica or flint, were to be regarded as oxides of elements of metallic
appearance. To complete our review of this part of the subject,
suffice it to say that aluminum, a metal now produced on an industrial
scale, was prepared for the first time in 1827 by Wöhler, professor of
chemistry at Göttingen, by the action of potassium on its chloride,
and alumina, the earthy basis of clay, was shown to be the oxide of
the metal aluminum. Indeed, the preparation of this metal in quantity
is now carried out at Schoffhausen-on-the-Rhine and at the Falls of
Foyers, in Scotland, by electrolysis of the oxide dissolved in melted
cryolite, a mineral consisting of the fluorides of sodium and aluminum,
by a method differing only in scale from that by means of which Davy
isolated sodium and potassium in 1806.
To Davy, too, belongs the merit of having dethroned oxygen from its
central position among the elements. Lavoisier gave to this important
gas the name “oxygen,” because he imagined it to be the constituent
of all acids. He renamed the common compounds of oxygen in such a
manner that the term oxygen was not even represented in the name—only
inferred. Thus a “nitrate” is a compound of an oxide of nitrogen
and an oxide of a metal; a “sulphate,” of the oxide of a metal with
one of the oxides of sulphur, and so on. Davy, by discovering the
elementary nature of chlorine, showed, first, that it is not an
oxide of hydrochloric acid (or muriatic acid as it was then called);
and, second, that the latter acid is the compound of the element
chlorine with hydrogen. This he did by passing chlorine over white-hot
carbon—a substance eminently suited to deprive oxy-compounds of their
oxygen—and proving that no oxide of carbon is thereby produced; by
acting on certain chlorides, such as those of tin or phosphorus with
ammonia, and showing that no oxide of tin or phosphorus is formed; and,
lastly, by decomposing “muriatic acid gas” (gaseous hydrogen chloride)
with sodium, and showing that the only product besides common salt is
hydrogen. Instead, therefore, of the former theory that a chloride was
a compound of the unknown basis of oxymuriatic acid with oxygen and
the oxide of a metal, he introduced the simpler and correct view that
a chloride is merely a compound of the element chlorine with a metal.
In 1813 he established the similar nature of fluorine, pointing out
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