The Working of Steel: Annealing, Heat Treating and Hardening of Carbon and Alloy SteelColvin, Fred H. (Fred Herbert)
Science
The Working of Steel: Annealing, Heat Treating and Hardening of Carbon and Alloy Steel
Colvin, Fred H. (Fred Herbert)
Steel
However, silicon, as noted above, burns very readily in oxygen,
and this property is of good use in steel making. At the end of
the steel-making process the metal contains more or less oxygen,
which must be removed. This is sometimes done (especially in the
so-called acid process) by adding a small amount of silicon to
the hot metal just before it leaves the furnace, and stirring it
in. It thereupon abstracts oxygen from the metal wherever it finds
it, changing to silica (SiO2) which rises and floats on the surface
of the cleaned metal. Most of the silicon remaining in the metal
is an excess over that which is required to remove the dangerous
oxygen, and the final analysis of many steels show enough silicon
(from 0.20 to 0.40) to make sure that this step in the manufacture
has been properly done.
MANGANESE is a metal much like iron. Its chemical symbol is Mn. It
is somewhat more active than iron in many chemical changes--notably
it has what is apparently a stronger attraction for oxygen and
sulphur than has iron. Therefore the metal is used (especially in
the so-called basic process) to free the molten steel of oxygen,
acting in a manner similar to silicon, as explained above. The
compound of manganese and oxygen is readily eliminated from the
metal. Sufficient excess of elemental manganese should remain so
that the purchaser may be sure that the iron has been properly
"deoxidized," and to render harmless the traces of sulphur present.
No damage is done by the presence of a little manganese in steel,
quite the reverse. Consequently it is common to find steels containing
from 0.3 to 1.5 per cent.
ALLOYING ELEMENTS.--Commercial steels of even the simplest types
are therefore primarily alloys of iron and carbon. Impurities and
their "remedies" are always present: sulphur, phosphorus, silicon
and manganese--to say nothing of oxygen, nitrogen and carbon oxide
gases, about which we know very little. It has been found that other
metals, if added to well-made steel, produce definite improvements
in certain directions, and these "alloy steels" have found much
use in the last ten years. Alloy steels, in addition to the
above-mentioned elements, may commonly contain one or more of the
following, in varying amounts: Nickel (Ni), Chromium (Cr), Vanadium
(Va), Tungsten (W), Molybdenum (Mo). These steels will be discussed
at more length in Chapters III and IV.
PROPERTIES OF STEEL
Steels are known by certain tests. Early tests were more or less
crude, and depended upon the ability of the workman to judge the
"grain" exhibited by a freshly broken piece of steel. The cold-bend
test was also very useful--a small bar was bent flat upon itself,
and the stretched fibers examined for any sign of break. Harder
stiff steels were supported at the ends and the amount of central
load they would support before fracture, or the amount of permanent
set they would acquire at a given load noted. Files were also used
to test the hardness of very hard steel.
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